Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system | |
Liu, Yong1,2; Chen, Lungang1; Wang, Tiejun1 ; Zhang, Xinghua1; Long, Jinxing1; Zhang, Qi1; Ma, Longlong1
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| 2015 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 5Issue:15Pages:11649-11657 |
| Abstract | In aqueous phosphoric acid, cellulose was efficiently converted into hexanes using a Ru/C catalyst combined with layered compounds or silica-alumina materials. In this process, the direct production of hexanes from cellulose can be improved by suppressing the formation of isosorbide, which makes it difficult to yield hexanes by further hydrodeoxygenation. As the co-catalyst, layered compounds showed a significant inhibition effect on the formation of isosorbide from sorbitol due to the steric restrictions of sorbitol dehydration within the interlayers of layered compounds. Typically, layered LiNbMoO6 played a great role in promoting the production of hexanes directly from cellulose and a promising yield (72% carbon mol) of hexanes was obtained. In addition, the protonic acid, H3PO4, offered efficient catalysis for the hydrolysis of cellulose and the dehydration of the sorbitol hydroxyl moiety. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c4ra14304c |
| WOS Subject Extended | Chemistry |
| WOS Keyword | TRANSITION-METAL OXIDE ; SOLID ACID CATALYSTS ; ONE-POT CONVERSION ; NI/HZSM-5 CATALYSTS ; ETHYLENE-GLYCOL ; GLYCOLALDEHYDE PHOSPHATE ; LIQUID ALKANES ; C-6 ALDITOLS ; RANEY NI ; BIOMASS |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000348986900095 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10805 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Yong,Chen, Lungang,Wang, Tiejun,et al. High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system[J]. RSC ADVANCES,2015,5(15):11649-11657. |
| APA | Liu, Yong.,Chen, Lungang.,Wang, Tiejun.,Zhang, Xinghua.,Long, Jinxing.,...&Ma, Longlong.(2015).High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system.RSC ADVANCES,5(15),11649-11657. |
| MLA | Liu, Yong,et al."High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system".RSC ADVANCES 5.15(2015):11649-11657. |
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