Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Selective Conversion of Cellulose into Ethylene Glycol over Metal-Organic Framework-Derived Multifunctional Catalysts | |
Wang, Shengpei1,2; Chen, Jinzhu1; Chen, Limin3 | |
2014-10-01 | |
Source Publication | CATALYSIS LETTERS |
Volume | 144Issue:10Pages:1728-1734 |
Abstract | A multifunctional catalyst of ruthenium supported on NENU-3 [a hybrid of phosphotungstic acid (PTA) and HKUST-1] is developed. An ethylene glycol (EG) yield of 50.2 % can be directly obtained from cellulose with Ru/NENU-3 as catalyst under optimized conditions. As a multifunctional catalyst of Ru/NENU-3, the presence of both the active specie of PTA for cellulose hydrolysis and subsequent C-C bond cleavage of cellulose-derived sugars, and the active specie of Ru for glycolaldehyde hydrogenation is indispensible for the formation of EG from cellulose. |
Subtype | Article |
Keyword | Cellulose Ethylene Glycol Metal-organic Frameworks Multifunctional Catalyst Ruthenium |
WOS Headings | Science & Technology ; Physical Sciences |
DOI | 10.1007/s10562-014-1334-1 |
WOS Subject Extended | Chemistry |
WOS Keyword | TUNGSTEN CARBIDE CATALYSTS ; BIMETALLIC CATALYSTS ; SUGAR ALCOHOLS ; BIOMASS ; CHEMICALS ; FUELS ; ACID ; NI |
Indexed By | SCI |
Language | 英语 |
WOS Subject | Chemistry, Physical |
WOS ID | WOS:000341859600011 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/10770 |
Collection | 中国科学院广州能源研究所 |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Wang, Shengpei,Chen, Jinzhu,Chen, Limin. Selective Conversion of Cellulose into Ethylene Glycol over Metal-Organic Framework-Derived Multifunctional Catalysts[J]. CATALYSIS LETTERS,2014,144(10):1728-1734. |
APA | Wang, Shengpei,Chen, Jinzhu,&Chen, Limin.(2014).Selective Conversion of Cellulose into Ethylene Glycol over Metal-Organic Framework-Derived Multifunctional Catalysts.CATALYSIS LETTERS,144(10),1728-1734. |
MLA | Wang, Shengpei,et al."Selective Conversion of Cellulose into Ethylene Glycol over Metal-Organic Framework-Derived Multifunctional Catalysts".CATALYSIS LETTERS 144.10(2014):1728-1734. |
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