Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2 | |
Yan, Chang-Feng1,2 ; Chen, Hao1,3; Hu, Rong-Rong1; Huang, Shilin1; Luo, Weimin1; Guo, Changqing1; Li, Mingyu3; Li, Wenbo1
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| 2014-10-31 | |
| Source Publication | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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| Volume | 39Issue:32Pages:18695-18701 |
| Abstract | Preferential oxidation of CO (CO-PrOx) is an important step to meet the need of the proton exchange membrane (PEM) fuel cell without the Pt anion poison. A glycine-nitrate approach was used for the synthesis of Co/CeO2 nanoparticle for preferential oxidation of CO, which a precursor solution was prepared by mixing glycine with an aqueous solution of blended nitrate in stoichiometric ratio. Then the glycine-mixed precursor solution was heated in a beaker for producing nanosized porous powders. Catalytic properties of the powders were investigated and results illustrate that the Co-loading of 30 wt.% catalysts exhibits excellent catalytic properties. Various characterization techniques like X-ray diffraction, SEM, BET, Raman and TPR were used to analyze the relationship between catalyst nature and catalytic performance. The X-ray diffraction patterns and SEM micrographs indicate that catalysts prepared by glycine-nitrate combustion own mesopore structure. The BET, Raman and TPR results showed that the high activity of the 30 wt.% Co-loading of Co/CeO2 catalysts is related to the high BET surface and the strongly interaction between fine-dispersed Co species and CeO2 support. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| Subtype | Article |
| Keyword | Co-prox Glycine-nitrate Combustion Co/ceo2 Catalyst |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.ijhydene.2014.01.024 |
| WOS Subject Extended | Chemistry ; Electrochemistry ; Energy & Fuels |
| WOS Keyword | CARBON-MONOXIDE OXIDATION ; HYDROGEN-RICH STREAM ; CO3O4-CEO2 CATALYSTS ; SELECTIVE OXIDATION ; STRUCTURAL-CHARACTERIZATION ; CUO-CEO2 CATALYSTS ; REACTION-MECHANISM ; ACTIVE CATALYSTS ; H-2-RICH GASES ; O COMPOSITE |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| WOS ID | WOS:000345804600059 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10757 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Jinan Univ, Dept Environm Engn, Guangzhou 510632, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Yan, Chang-Feng,Chen, Hao,Hu, Rong-Rong,et al. Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2014,39(32):18695-18701. |
| APA | Yan, Chang-Feng.,Chen, Hao.,Hu, Rong-Rong.,Huang, Shilin.,Luo, Weimin.,...&Li, Wenbo.(2014).Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,39(32),18695-18701. |
| MLA | Yan, Chang-Feng,et al."Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 39.32(2014):18695-18701. |
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