Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| One-Step Approach to 2,5-Diformylfuran from Fructose by Proton-and Vanadium-Containing Graphitic Carbon Nitride | |
Chen, Jinzhu1,3 ; Guo, Yuanyuan1; Chen, Jiayi1; Song, Lu2; Chen, Limin2
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| 2014-11-01 | |
| Source Publication | CHEMCATCHEM
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| Volume | 6Issue:11Pages:3174-3181 |
| Abstract | 5-Hydroxymethylfurfural (HMF) was selectively synthesized from fructose by using protonated graphitic carbon nitride [g-C3N4(H+)] as a solid acid. With g-C3N4 as the same precursor material, 2,5-diformylfuran (DFF) was efficiently obtained from aerobic oxidation of HMF by using vanadium-doped g-C3N4 (V-g-C3N4) as an environmentally benign heterogeneous catalyst with atmospheric pressure of molecular oxygen as the oxidant. In addition, a combination of g-C3N4(H+) and V-g-C3N4 successfully afforded the direct synthesis of DFF from fructose through g-C3N4(H+)-promoted fructose dehydration and V-gC(3)N(4)-catalyzed successively aerobic oxidation of HMF to DFF in a one-pot and two-step process. Moreover, a bifunctional catalyst made of protonated V-g-C3N4 [V-g-C3N4(H+)] allowed one-pot as well as one-step direct transformation of fructose into DFF. Under optimized conditions, 80% yield of HMF and 82% yield of DFF were obtained from g-C3N4(H+)-promoted fructose dehydration and V-g-C3N4-catalyzed HMF oxidation, respectively. Stepwise addition of g-C3N4(H+) and V-g-C3N4 in the one-pot process improved the DFF yield up to 63% from fructose. In contrast, V-g-C3N4(H+)-catalyzed direct one-step transformation of fructose into DFF led to a DFF yield of 45 %. The research highlights a one-step approach to DFF from fructose with functional g-C3N4 catalyst. |
| Subtype | Article |
| Keyword | Biomass Carbon Nitrides Oxidation Vanadium |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cctc.201402323 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | EFFICIENT AEROBIC OXIDATION ; SOLID ACID CATALYSTS ; ONE-POT SYNTHESIS ; BIOMASS ; CHEMICALS ; DERIVATIVES ; CONVERSION ; FUELS ; 5-HYDROXYMETHYL-2-FURALDEHYDE ; PHOTOCATALYSIS |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000344330800023 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10734 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Chen, Jinzhu,Guo, Yuanyuan,Chen, Jiayi,et al. One-Step Approach to 2,5-Diformylfuran from Fructose by Proton-and Vanadium-Containing Graphitic Carbon Nitride[J]. CHEMCATCHEM,2014,6(11):3174-3181. |
| APA | Chen, Jinzhu,Guo, Yuanyuan,Chen, Jiayi,Song, Lu,&Chen, Limin.(2014).One-Step Approach to 2,5-Diformylfuran from Fructose by Proton-and Vanadium-Containing Graphitic Carbon Nitride.CHEMCATCHEM,6(11),3174-3181. |
| MLA | Chen, Jinzhu,et al."One-Step Approach to 2,5-Diformylfuran from Fructose by Proton-and Vanadium-Containing Graphitic Carbon Nitride".CHEMCATCHEM 6.11(2014):3174-3181. |
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