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Synthesis Gas Production by Chemical-Looping Reforming of Methane Using Lattice Oxygen
Huang Zhen; He Fang; Zhao Kun; Zheng Anqing; Li Haibin; Zhao Zengli
2012-08-24
Source PublicationPROGRESS IN CHEMISTRY
Volume24Issue:8Pages:1599-1609
AbstractChemical looping reforming (CLR) of methane to obtain synthesis gas using lattice oxygen of oxygen carriers instead of molecular oxygen is a novel technology for producing synthesis gas from methane, which has higher economic benefits and environmental benign. CLR has several advantages, such as, saving oxygen generation equipment, capable of self-heating, suitable hydrogen/carbon ratio, useful by-products and realizing industrialization easily, so, it has been growing interest for researchers at home and aboard. Firstly, the basic concept and characteristics of CLR are introduced, which is partial oxidation of methane through controlling the value of lattice oxygen/fuel, thus, the synthesis gas is produced through the gas-solid reaction between methane and oxygen carriers, and the reduced oxygen carriers are re-oxidized by air or H2O to restore its lattice oxygen. Direct contact between fuel and combustion air is avoided in the CLR. Instead, an oxygen carrier performs the task of bringing O-2 from the air to the fuel. In particular, it is summarized for the research progress of monometallic and composite metal oxygen carriers. And the same time, several kinds of typical representative reactor in CLR are discussed, among which interconnected fluidized bed reactor will be most effective for CLR to realize industrialization in the future. Finally, the expand application of CLR and the trends coupled with other technology are prospected.
SubtypeArticle
KeywordMethane Chemical Looping Reforming Synthesis Gas Lattice Oxygen Reactor
WOS HeadingsScience & Technology ; Physical Sciences
WOS Subject ExtendedChemistry
WOS KeywordFLUIDIZED-BED REACTOR ; SUPPORTED NI CATALYSTS ; PARTIAL OXIDATION ; HYDROGEN-PRODUCTION ; CERIUM OXIDE ; METAL-OXIDES ; CO2 CAPTURE ; COMBUSTION ; CARRIERS ; GENERATION
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000308508600019
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10586
Collection中国科学院广州能源研究所
AffiliationChinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Huang Zhen,He Fang,Zhao Kun,et al. Synthesis Gas Production by Chemical-Looping Reforming of Methane Using Lattice Oxygen[J]. PROGRESS IN CHEMISTRY,2012,24(8):1599-1609.
APA Huang Zhen,He Fang,Zhao Kun,Zheng Anqing,Li Haibin,&Zhao Zengli.(2012).Synthesis Gas Production by Chemical-Looping Reforming of Methane Using Lattice Oxygen.PROGRESS IN CHEMISTRY,24(8),1599-1609.
MLA Huang Zhen,et al."Synthesis Gas Production by Chemical-Looping Reforming of Methane Using Lattice Oxygen".PROGRESS IN CHEMISTRY 24.8(2012):1599-1609.
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