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Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound
Shi, Na; Liu, Qi-ying; Jiang, Ting; Wang, Tie-jun; Ma, Long-long; Zhang, Qi; Zhang, Xing-hua
2012-04-05
Source PublicationCATALYSIS COMMUNICATIONS
Volume20Pages:80-84
AbstractNi/HZSM-5 catalysts with different Ni loadings were prepared by impregnation method, and their catalytic performance was evaluated in the hydrodeoxygenation (HDO) upgrading of the model reactant methyl hexadecanoate (MHD) to liquid alkane fuels. The physicochemical properties of the catalysts were characterized by XRD, SEM, NH3-TPD, and BET. Ni loadings were obviously influenced by the acidity, and thus significantly affected their catalytic performance. Over 7 wt.% Ni/HZSM-5 catalyst, MHD conversion of more than 90% and total liquid C-5-C-16 hydrocarbon selectivity of 83% were obtained under the optimum reaction condition, possibly due to the synergistic effect of metal Ni and acid HZSM-5. (C) 2012 Elsevier B.V. All rights reserved.
SubtypeArticle
KeywordHydrodeoxygenation Methyl Hexadecanoate Biofuels Ni/hzsm-5 Catalyst
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.catcom.2012.01.007
WOS Subject ExtendedChemistry
WOS KeywordSULFIDED NIMO/GAMMA-AL2O3 ; ALIPHATIC ESTERS ; HYDROISOMERIZATION ; PERFORMANCE ; DIESEL ; ACID
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical
WOS IDWOS:000302110700017
Citation statistics
Cited Times:51[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10562
Collection中国科学院广州能源研究所
AffiliationChinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Shi, Na,Liu, Qi-ying,Jiang, Ting,et al. Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound[J]. CATALYSIS COMMUNICATIONS,2012,20:80-84.
APA Shi, Na.,Liu, Qi-ying.,Jiang, Ting.,Wang, Tie-jun.,Ma, Long-long.,...&Zhang, Xing-hua.(2012).Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound.CATALYSIS COMMUNICATIONS,20,80-84.
MLA Shi, Na,et al."Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound".CATALYSIS COMMUNICATIONS 20(2012):80-84.
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