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Effect of doping mode on the photocatalytic activities of Mo/TiO2
Yang, Y; Li, XJ; Chen, JT; Wang, LY
2004-05-21
Source PublicationJOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume163Issue:3Pages:517-522
AbstractThe thin films of photocatalyst, TiO2 doped by Mo6+ in different forms, were prepared by sol-gel method. The photocatalysts were characterized by X-ray diffraction (XRD), UV-Vis transmittance spectra and electrochemical impedance spectroscopy, and the photocatalytic activity was characterized by photocatalytic degradation of aqueous methyl orange under UV radiation. The results showed that the TiO2, doped by Mo6+ extend absorption edge and interfacial charge transfer resistance decrease. The photocatalytic activity of TiO2 doped by Mo6+ in bottom is much better than that of pure TiO2, those doped in surface, or those doped uniformly. The activity of TiO2 doped by Mo6+ in bottom mode at optimal concentration, 1 at.%, increased nearly two times than pure TiO2. The effects of doping modes on the photocatalytic activities were discussed in the terms of separateness of charge carriers that there maybe form barrier of carrier in bottom doping mode and then restraining the (e(-)-h(+)) pair recombination. (C) 2004 Elsevier B.V All rights reserved.
SubtypeArticle
KeywordPhotocatalysis Titanium Dioxide Molybdenum Doping Mode Thin Film
WOS HeadingsScience & Technology ; Physical Sciences
WOS Subject ExtendedChemistry
WOS KeywordTIO2
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical
WOS IDWOS:000221685700030
Citation statistics
Cited Times:197[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10488
Collection中国科学院广州能源研究所
AffiliationChinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Yang, Y,Li, XJ,Chen, JT,et al. Effect of doping mode on the photocatalytic activities of Mo/TiO2[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2004,163(3):517-522.
APA Yang, Y,Li, XJ,Chen, JT,&Wang, LY.(2004).Effect of doping mode on the photocatalytic activities of Mo/TiO2.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,163(3),517-522.
MLA Yang, Y,et al."Effect of doping mode on the photocatalytic activities of Mo/TiO2".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 163.3(2004):517-522.
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