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Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface
Li, XJ; Li, FB; Gu, GB; Liu, S; Wang, LY; Liang, YY
2003-04-01
Source PublicationTRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume13Issue:2Pages:448-451
AbstractBased on the infrared characterization of methyl orange adsorption on TiO2 surface and the titration of TiO2, the triple layer model of methyl orange adsorption on TiO2 was established according to electric double theory. The software FITEQL3. 1 was applied to calculate the distribution of organic adsorption on TiO2 surface by introducing dummy components to help to overcome mathematical difficulties. It is shown that the chem. -adsorption species of methyl orange have a great adsorption amount. The adsorption constants of three kinds of surface complexation expressed as SOH+ org(-), SOH2 org(2) and SOHorg(-) are 5. 98, 17. 57 and - 4. 2, respectively.
SubtypeArticle
KeywordAdsorption Methyl Orange Tio2 Surface Complexation Photocatalysis
WOS HeadingsScience & Technology ; Technology
WOS Subject ExtendedMetallurgy & Metallurgical Engineering
WOS KeywordPHOTO-CATALYTIC BEHAVIOR ; SEMICONDUCTOR NANOPOWDER ; TITANIUM-DIOXIDE ; INTERFACE
Indexed BySCI
Language英语
WOS SubjectMetallurgy & Metallurgical Engineering
WOS IDWOS:000182726000044
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10469
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Peoples R China
2.Guangdong Inst Ecoenvironm & Soil Sci, Guangdong Key Lab Agr Environm Pollut Integrated, Guangzhou 510650, Peoples R China
3.S China Univ Technol, Dept Appl Chem, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Li, XJ,Li, FB,Gu, GB,et al. Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2003,13(2):448-451.
APA Li, XJ,Li, FB,Gu, GB,Liu, S,Wang, LY,&Liang, YY.(2003).Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,13(2),448-451.
MLA Li, XJ,et al."Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 13.2(2003):448-451.
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