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Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge
Tian, FJ; Li, BQ; Chen, Y; Li, CZ
2002-12-01
Source PublicationFUEL
Volume81Issue:17Pages:2203-2208
AbstractA sewage sludge sample from a wastewater treatment plant in China was pyrolysed in a fluidised-bed/fixed-bed reactor and in a fluidised-bed/tubular reactor. HCN was found to be the main NOx precursor, representing up to about 80% of the nitrogen present in the sludge. The thermal cracking of volatiles is the main route of HCN formation. NH3 was also an important NOx precursor formed during the pyrolysis of the sewage sludge. The experimental results indicate that there are at least two distinctive stages of NH3 formation during the pyrolysis of the sewage sludge at a fast heating rate. The formation of NH3 at temperatures lower than 400-500 degreesC is at least partly due to the amino structures in the sludge. The reactions of volatiles in the gas phase make negligible contributions to the observed NH3 yield. (C) 2002 Elsevier Science Ltd. All rights reserved.
SubtypeArticle
KeywordHcn Nh3 Nox Precursors Sewage Sludge And Pyrolysis
WOS HeadingsScience & Technology ; Technology
WOS Subject ExtendedEnergy & Fuels ; Engineering
WOS KeywordFLUIDIZED-BED ; SOX PRECURSORS ; WASTE MATERIALS ; HCN ; NH3 ; INCINERATION ; COMBUSTION ; CHEMICALS ; RELEASE ; REACTOR
Indexed BySCI
Language英语
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000178414200009
Citation statistics
Cited Times:135[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10456
Collection中国科学院广州能源研究所
Affiliation1.Monash Univ, CRC Clean Power Lignite, Clayton, Vic 3800, Australia
2.Chinese Acad Sco, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Shanxi, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Tian, FJ,Li, BQ,Chen, Y,et al. Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge[J]. FUEL,2002,81(17):2203-2208.
APA Tian, FJ,Li, BQ,Chen, Y,&Li, CZ.(2002).Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge.FUEL,81(17),2203-2208.
MLA Tian, FJ,et al."Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge".FUEL 81.17(2002):2203-2208.
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