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Pyrolysis of tire powder: influence of operation variables on the composition and yields of gaseous product
Leung, DYC; Yin, XL; Zhao, ZL; Xu, BY; Chen, Y
2002-10-20
Source PublicationFUEL PROCESSING TECHNOLOGY
Volume79Issue:2Pages:141-155
AbstractThe pyrolysis of tire powder was studied experimentally using a specially designed pyrolyzer with high heating rates. The composition and yield of the derived gases and distribution of the pyrolyzed product were determined at temperatures between 500 and 1000 degreesC under different gas phase residence times. It is found that the gas yield goes up while the char and tar yield decrease with increasing temperature. The gaseous product mainly consists of H-2, CO, CO2, H2S and hydrocarbons such as CH4, C2H4, C2H6, C3H6, C3H8, C4H8 and C4H6 with a little other hydrocarbon gases. Its 3 heating value is in the range of 20 to 37 MJ/Nm(3). Maximum heating value is achieved at a temperature between 700 and 800 degreesC. The product distribution ratio of gas, tar and char is about 21:44:35 at 800 degreesC. The gas yield increases with increasing gas residence time when temperature of the residence zone is higher than 700 degreesC. The gas heating value shows the opposite trend when the temperature is higher than 800 degreesC. Calcined dolomite and limestone were used to explore their effect on pyrolyzed product distribution and composition of the gaseous product. It is found that both of them affect the product distribution, but the effect on tar cracking is not obvious when the temperature is lower than 900 degreesC. It is also found that H2S can be absorbed effectively by using either of them. About 57% sulfur is retained in the char and 6% in the gas phase. The results indicated that high-energy recovery could not be achieved if fuel gas is the only target product. In view of this, multi-use of the pyrolyzed product is highly recommended. (C) 2002 Elsevier Science B.V. All rights reserved.
SubtypeArticle
KeywordPyrolysis Tire Gas Yield Gas Residence Time Catalyst
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS Subject ExtendedChemistry ; Energy & Fuels ; Engineering
WOS KeywordSCRAP TIRES ; AUTOMOTIVE TIRES ; HEATING-RATE ; BED REACTOR ; CARBON ; WASTE
Indexed BySCI
Language英语
WOS SubjectChemistry, Applied ; Energy & Fuels ; Engineering, Chemical
WOS IDWOS:000177965600006
Citation statistics
Cited Times:124[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10452
Collection中国科学院广州能源研究所
Affiliation1.Univ Hong Kong, Dept Mech Engn, Hong Kong, Hong Kong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Peoples R China
Recommended Citation
GB/T 7714
Leung, DYC,Yin, XL,Zhao, ZL,et al. Pyrolysis of tire powder: influence of operation variables on the composition and yields of gaseous product[J]. FUEL PROCESSING TECHNOLOGY,2002,79(2):141-155.
APA Leung, DYC,Yin, XL,Zhao, ZL,Xu, BY,&Chen, Y.(2002).Pyrolysis of tire powder: influence of operation variables on the composition and yields of gaseous product.FUEL PROCESSING TECHNOLOGY,79(2),141-155.
MLA Leung, DYC,et al."Pyrolysis of tire powder: influence of operation variables on the composition and yields of gaseous product".FUEL PROCESSING TECHNOLOGY 79.2(2002):141-155.
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