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Origin of efficiency enhancement in Nb2O5 coated titanium dioxide nanorod based dye sensitized solar cells
Barea, Eva1; Xu, Xueqing1,2; Gonzalez-Pedro, Victoria1; Ripolles-Sanchis, Teresa1; Fabregat-Santiago, Francisco1; Bisquert, Juan1
2011-09-01
Source PublicationENERGY & ENVIRONMENTAL SCIENCE
Volume4Issue:9Pages:3414-3419
AbstractOrdered one-dimensional metal oxides are considered promising architectures for dye-sensitized solar cells (DSC). Here we explore the properties determining the photovoltaic performance of DSC based on titanium dioxide nanorods prepared by a hydrothermal method. Ultrathin conformal coating with other oxides such as Al2O3 or Nb2O5 has been widely used in the literature to improve the conversion efficiency. Usually the effects attributed to the coating are either to prevent recombination by barrier effect or to change the position of titanium dioxide conduction band. Here we show that coating TiO2 nanorods with Nb2O5 increases the photocurrent and conversion efficiency of the DSC. However, impedance spectroscopy results indicate that neither recombination is reduced by the coating nor the conduction band position is moved. The improvement in the performance of the cell has been attributed to an enhancement in the charge injection efficiency promoted by Nb2O5.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology ; Life Sciences & Biomedicine
DOI10.1039/c1ee01193f
WOS Subject ExtendedChemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
WOS KeywordIMPEDANCE SPECTROSCOPY ; NANOPOROUS ELECTRODES ; NANOWIRE ARRAYS ; RECOMBINATION ; PERFORMANCE ; NANOTUBES ; TRANSPORT ; ANODIZATION ; FABRICATION ; CONVERSION
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS IDWOS:000294306900032
Citation statistics
Cited Times:74[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10369
Collection中国科学院广州能源研究所
Affiliation1.Univ Jaume 1, Dept Fis, Grp Dispositius Fotovolta & Optoelect, Castellon de La Plana, Spain
2.Chinese Acad Sci, Renewable Energy & Gas Hydrate Key Lab, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Barea, Eva,Xu, Xueqing,Gonzalez-Pedro, Victoria,et al. Origin of efficiency enhancement in Nb2O5 coated titanium dioxide nanorod based dye sensitized solar cells[J]. ENERGY & ENVIRONMENTAL SCIENCE,2011,4(9):3414-3419.
APA Barea, Eva,Xu, Xueqing,Gonzalez-Pedro, Victoria,Ripolles-Sanchis, Teresa,Fabregat-Santiago, Francisco,&Bisquert, Juan.(2011).Origin of efficiency enhancement in Nb2O5 coated titanium dioxide nanorod based dye sensitized solar cells.ENERGY & ENVIRONMENTAL SCIENCE,4(9),3414-3419.
MLA Barea, Eva,et al."Origin of efficiency enhancement in Nb2O5 coated titanium dioxide nanorod based dye sensitized solar cells".ENERGY & ENVIRONMENTAL SCIENCE 4.9(2011):3414-3419.
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