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The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate
Xu, X. Q.; Shen, H.; Xu, J. R.; Xie, M. Q.; Li, X. J.
2006-12-15
Source PublicationAPPLIED SURFACE SCIENCE
Volume253Issue:4Pages:2158-2164
AbstractThe adsorption of alginate (Alg) onto the surface of in water dispersed Fe3O4 nanoparticles and zeta potential of alginate-coated Fe3O4 nanoparticles have been investigated to optimize the colloidal stability of Alg-coated Fe3O4 nanoparticles. The adsorption amount of Alg increased with the decrease of adsorption pH. The zeta potential of Fe3O4 nanoparticles shifted to a lower value after adsorption of Alg. The lower adsorption pH was the lower zeta potential of Fe3O4 nanoparticles became. The Alg-coated Fe3O4 nanoparticles were found to be stabilized by steric and electrostatic repulsions. Those prepared at pH 6 were not stable around pH 5, and those prepared at pH 4 became unstable at pH below 3.5. Alg of M-w 45 kDa was a little bit more adsorbed onto nanoparticles surface than that of Mw 24 kDa. An average Fe3O4 core size of 9.3 +/- 1.7 nm was found by transmission electronic microscopy. An average hydrodynamic diameter of 30-150 nm was measured by photon correlation spectroscopy. However, an average core size of 10 rim and an average hydrodynamic diameter of 38 nm were estimated from the magnetization curve of the concentrated magnetic fluids (MFs). The maximum available saturation magnetization of MFs was about 3.5 kA/m. (c) 2006 Elsevier B.V. All rights reserved.
SubtypeArticle
KeywordMagnetite Nanoparticles Alginate Adsorption Zeta Potential Stability Structure
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.apsusc.2006.04.015
WOS Subject ExtendedChemistry ; Materials Science ; Physics
WOS KeywordSURFACE ; POLYMER
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000243244200080
Citation statistics
Cited Times:81[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10261
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Sun Yat Sen Univ, Sch Phys & Engn, Guangzhou 510275, Peoples R China
3.Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
4.Sun Yat Sen Univ, Affiliated Hosp 3, Guangzhou 510630, Peoples R China
Recommended Citation
GB/T 7714
Xu, X. Q.,Shen, H.,Xu, J. R.,et al. The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate[J]. APPLIED SURFACE SCIENCE,2006,253(4):2158-2164.
APA Xu, X. Q.,Shen, H.,Xu, J. R.,Xie, M. Q.,&Li, X. J..(2006).The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate.APPLIED SURFACE SCIENCE,253(4),2158-2164.
MLA Xu, X. Q.,et al."The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate".APPLIED SURFACE SCIENCE 253.4(2006):2158-2164.
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