Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Photocatalytic activity of TiO2 thin film non-uniformly doped by Ni | |
| Yu, H; Li, XJ; Zheng, SJ; Xu, W | |
| 2006-05-10 | |
| Source Publication | MATERIALS CHEMISTRY AND PHYSICS
 |
| Volume | 97Issue:1Pages:59-63 |
| Abstract | The thin films of TiO2 doped by Ni non-uniformly were prepared by a modified dip-hoisting process of sol-gel method. The transmittance, absorbency, photocurrent and open-circuit potential of the thin films were studied by UV-vis spectrophotometer and electrochemical workstation. The activity of thin films was characterized by photocatalytic degradation of aqueous methyl orange under UV irradiation. The results showed that the photocatalytic activity of TiO2 thin films can be remarkably enhanced by Ni non-uniformly doping compared with the pure ones, while that of the uniformly doped can only be improved a little. The transmittance of the TiO2 thin films doped by Ni uniformly and non-uniformly doping showed '' blue shift '' and '' red shift '', respectively. The absorbency of the non-uniformly doped extended to '' red shift ''. Under UV irradiation, the non-uniformly doped TiO2 thin films show higher open-circuit potential and photocurrent compared with that of the pure ones, which demonstrated that the photogenerated electron-hole pairs were effectively separated. And the electrode bias influenced the photocurrent of Ni non-uniformly doped TiO2 thin films greatly, which verified the structure of p-n junction. The photocatalytic activity mechanism of the non-uniformly doped TiO2 was discussed by p-n junction theory. (c) 2005 Elsevier B.V. All rights reserved. |
| Subtype | Article |
| Keyword | Photocatalyst Tio2 Thin Films Non-uniformity Ni Doping |
| WOS Headings | Science & Technology ; Technology |
| DOI | 10.1016/j.matchemphys.2005.07.069 |
| WOS Subject Extended | Materials Science |
| WOS Keyword | PHOTODEGRADATION ; PHOTOREDUCTION ; DINITROGEN ; TITANIA ; PHENOL |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Materials Science, Multidisciplinary |
| WOS ID | WOS:000236458400010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10257 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Yu, H,Li, XJ,Zheng, SJ,et al. Photocatalytic activity of TiO2 thin film non-uniformly doped by Ni[J]. MATERIALS CHEMISTRY AND PHYSICS,2006,97(1):59-63. |
| APA | Yu, H,Li, XJ,Zheng, SJ,&Xu, W.(2006).Photocatalytic activity of TiO2 thin film non-uniformly doped by Ni.MATERIALS CHEMISTRY AND PHYSICS,97(1),59-63. |
| MLA | Yu, H,et al."Photocatalytic activity of TiO2 thin film non-uniformly doped by Ni".MATERIALS CHEMISTRY AND PHYSICS 97.1(2006):59-63. |
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