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Corrosion inhibition of copper-phosphorus brazing alloys in tetra-n-butylammonium bromide aerated aqueous solution by benzotriazole
Liu, S.1; Guan, W. W.1; Yan, Y. H.1; Jiang, R. Y.1; Feng, Z. P.2; Song, W. J.2; Qin, K.2
2013-10-01
Source PublicationMATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
Volume64Issue:10Pages:932-939
AbstractThe corrosion inhibition behavior of benzotriazole (BTA) on a brazing alloy, CuP in the non-welded and welded conditions in 17wt% (0.534mol/L) tetra-n-butylammonium bromide (TBAB) aerated aqueous solution was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy/energy dispersive X-ray spectroscopy techniques. The experimental results showed that BTA could protect effectively copper alloys in aqueous TBAB solution. The inhibition efficiency of BTA increased with increasing inhibitor concentration from 0.1 to 6g/L, attaining efficiencies of up to 96% calculated according to different methodologies. Corrosion current densities were lower after the melting process. Galvanic studies showed that copper behaved as the anode when coupled to its alloys. The addition of BTA caused an increase in charge transfer resistance and a decrease in the capacitance of the double layer. Adsorption of BTA in 17wt% TBAB solution on the copper alloys' surface was found to obey the Langmuir adsorption isotherm.
SubtypeArticle
KeywordBenzotriazole Copper Inhibition Tetra-n-butylammonium Bromide Welding
WOS HeadingsScience & Technology ; Technology
DOI10.1002/maco.201106436
WOS Subject ExtendedMaterials Science ; Metallurgy & Metallurgical Engineering
WOS KeywordRAMAN-SPECTROSCOPY ; CHLORIDE SOLUTION ; HYDRATE CRYSTALS ; BEHAVIOR ; FILMS ; ACID ; ADSORPTION ; IMPEDANCE ; KINETICS ; SULFATE
Indexed BySCI
Language英语
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000327742100010
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10132
Collection中国科学院广州能源研究所
Affiliation1.S China Univ Technol, Dept Appl Chem, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Liu, S.,Guan, W. W.,Yan, Y. H.,et al. Corrosion inhibition of copper-phosphorus brazing alloys in tetra-n-butylammonium bromide aerated aqueous solution by benzotriazole[J]. MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,2013,64(10):932-939.
APA Liu, S..,Guan, W. W..,Yan, Y. H..,Jiang, R. Y..,Feng, Z. P..,...&Qin, K..(2013).Corrosion inhibition of copper-phosphorus brazing alloys in tetra-n-butylammonium bromide aerated aqueous solution by benzotriazole.MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,64(10),932-939.
MLA Liu, S.,et al."Corrosion inhibition of copper-phosphorus brazing alloys in tetra-n-butylammonium bromide aerated aqueous solution by benzotriazole".MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION 64.10(2013):932-939.
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