Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation | |
Zhang, Xinghua1,2 ; Wang, Tiejun1; Ma, Longlong1; Zhang, Qi1; Yu, Yuxiao1,2; Liu, Qiying1
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| 2013-03-05 | |
| Source Publication | CATALYSIS COMMUNICATIONS
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| Volume | 33Pages:15-19 |
| Abstract | ZrO2-SiO2 complex oxides with Si/Zr mole ratio of 3 (SZ-3) were synthesized. ZrO2-SiO2 supported Ni and NiCu catalysts were prepared by impregnation method. Their catalytic performances were evaluated in the hydrodeoxygenation (HDO) upgrading of model reactant guaiacol to hydrocarbons. The physicochemical properties of the support materials and catalysts were characterized by FTIR, XRD, TPD, TPR, and BET techniques. The addition of Cu significantly affected the acidity, and thus influenced their catalytic performance for product distributions. Over the Ni5Cu/SZ-3 catalyst, the cyclohexane selectivity of 80.8% and the methylcyclohexane selectivity of 12.4% were obtained with complete conversion of guaiacol under the 300 degrees C, 5.0 MPa H-2 pressure. (C) 2012 Elsevier B.V. All rights reserved. |
| Subtype | Article |
| Keyword | Catalyst Zro2-sio2 Guaiacol Hydrodeoxygenation (Hdo) |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.catcom.2012.12.011 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | NOBLE-METAL CATALYSTS ; PYROLYSIS OIL ; LIGNIN ; BENZOFURAN ; NICKEL |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000316583700004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10125 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,et al. Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation[J]. CATALYSIS COMMUNICATIONS,2013,33:15-19. |
| APA | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,Zhang, Qi,Yu, Yuxiao,&Liu, Qiying.(2013).Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation.CATALYSIS COMMUNICATIONS,33,15-19. |
| MLA | Zhang, Xinghua,et al."Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation".CATALYSIS COMMUNICATIONS 33(2013):15-19. |
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