Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Directional synthesis of ethylbenzene through catalytic transformation of lignin | |
| Fan, Minghui1; Jiang, Peiwen1; Bi, Peiyan1; Deng, Shumei1; Yan, Lifeng1; Zhai, Qi1; Wang, Tiejun2; Li, Quanxin1 | |
| 2013-09-01 | |
| Source Publication | BIORESOURCE TECHNOLOGY
 |
| Volume | 143Pages:59-67 |
| Abstract | Transformation of lignin to ethylbenzene can provide an important bulk raw material for the petrochemical industry. This work explored the production of ethylbenzene from lignin through the directional catalytic depolymerization of lignin into the aromatic monomers followed by the selective alkylation of the aromatic monomers. For the first step, the aromatics selectivity of benzene derived from the catalytic depolymerization of lignin reached about 90.2 C-mol% over the composite catalyst of Re-Y/HZSM-5 (25). For the alkylation of the aromatic monomers in the second step, the highest selectivity of ethylbenzene was about 72.3 C-mol% over the HZSM-5 (25) catalyst. The reaction pathway for the transformation of lignin to ethylbenzene was also addressed. Present transformation potentially provides a useful approach for the production of the basic petrochemical material and development of high-end chemicals utilizing lignin as the abundant natural aromatic resource. (C) 2013 Elsevier Ltd. All rights reserved. |
| Subtype | Article |
| Keyword | Lignin Ethylbenzene Aromatic Monomer Depolymerization Alkylation |
| WOS Headings | Science & Technology ; Life Sciences & Biomedicine ; Technology |
| DOI | 10.1016/j.biortech.2013.05.097 |
| WOS Subject Extended | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| WOS Keyword | LIGHT OLEFINS ; BIO-OIL ; ALKYLATION ; BENZENE ; ZEOLITE ; CONVERSION ; DEPOLYMERIZATION ; ETHYLATION ; AROMATICS ; OXIDATION |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| WOS ID | WOS:000323239800009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10116 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Univ Sci & Technol China, Anhui Key Lab Biomass Clean Energy, Dept Chem Phys, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Fan, Minghui,Jiang, Peiwen,Bi, Peiyan,et al. Directional synthesis of ethylbenzene through catalytic transformation of lignin[J]. BIORESOURCE TECHNOLOGY,2013,143:59-67. |
| APA | Fan, Minghui.,Jiang, Peiwen.,Bi, Peiyan.,Deng, Shumei.,Yan, Lifeng.,...&Li, Quanxin.(2013).Directional synthesis of ethylbenzene through catalytic transformation of lignin.BIORESOURCE TECHNOLOGY,143,59-67. |
| MLA | Fan, Minghui,et al."Directional synthesis of ethylbenzene through catalytic transformation of lignin".BIORESOURCE TECHNOLOGY 143(2013):59-67. |
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