Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media | |
| Chen, Aibing1; Zhao, Guoying1,2; Chen, Jinzhu2; Chen, Limin3; Yu, Yifeng1 | |
| 2013 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 3Issue:13Pages:4171-4175 |
| Abstract | A combination of "water soluble'' palladium nanoparticles stabilized by an ionic liquid-like copolymer and phosphotungstic acid synergistically promotes selective hydrogenation of phenol to cyclohexanone. The nanocatalyst preparation and selective phenol hydrogenation are successfully combined into a one-pot process in this research. Conversion exceeding 99% was achieved with >99% selectivity under an atmospheric pressure of hydrogen in aqueous media. Moreover, even at room temperature, >99% conversion and >99% selectivity could still be obtained. The generality of the catalyst system for this reaction was demonstrated by selective hydrogenation of other hydroxylated aromatic compounds with similar performance. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c3ra21663b |
| WOS Subject Extended | Chemistry |
| WOS Keyword | SUPERCRITICAL CARBON-DIOXIDE ; SUPPORTED PD ; HETEROGENEOUS CATALYSIS ; CYCLOHEXANE OXIDATION ; BENZENE ; PHASE ; METAL ; PRECURSORS ; SILICA ; STATE |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000315818200009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10102 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Aibing,Zhao, Guoying,Chen, Jinzhu,et al. Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media[J]. RSC ADVANCES,2013,3(13):4171-4175. |
| APA | Chen, Aibing,Zhao, Guoying,Chen, Jinzhu,Chen, Limin,&Yu, Yifeng.(2013).Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media.RSC ADVANCES,3(13),4171-4175. |
| MLA | Chen, Aibing,et al."Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media".RSC ADVANCES 3.13(2013):4171-4175. |
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