Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media | |
| Chen, Jinzhu1; Huang, Jing1; Chen, Limin2; Ma, Longlong1; Wang, Tiejun1; Zakai, Uzma I.1 | |
| 2013-06-01 | |
| Source Publication | CHEMCATCHEM
 |
| Volume | 5Issue:6Pages:1598-1605 |
| Abstract | Using phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. Here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer A-stabilized nanocatalysts and the mineral acid H3PO4. The developed Ru/A-H3PO4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. Mercury poisoning experiments revealed that the insitu generated Ru nanoparticles are true a heterogeneous catalyst for hydrogenation. The catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of Ru>Rh>Pt >> Pd. Our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. The research highlights an efficient catalyst system of transforming phenols into alkanes. |
| Subtype | Article |
| Keyword | Biomass Heterogeneous Catalysis Hydrodeoxygenation Ionic Liquids Phenol |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cctc.201200582 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | FAST PYROLYSIS PROCESSES ; BIO-OILS ; BIOMASS ; CATALYSTS ; ALKANES ; HYDROGENATION ; COMPLEXES ; METAL |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000319680800049 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10101 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. CHEMCATCHEM,2013,5(6):1598-1605. |
| APA | Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.CHEMCATCHEM,5(6),1598-1605. |
| MLA | Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".CHEMCATCHEM 5.6(2013):1598-1605. |
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