Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials | |
Liu, Ruliang1,3; Chen, Jinzhu1 ; Huang, Xing1; Chen, Limin2; Ma, Longlong1; Li, Xinjun1
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| 2013 | |
| Source Publication | GREEN CHEMISTRY
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| Volume | 15Issue:10Pages:2895-2903 |
| Abstract | A series of sulfonic acid-functionalized carbon materials (C-SO3H), including poly(p-styrenesulfonic acid)-grafted carbon nanotubes (CNT-PSSA), poly(p-styrenesulfonic acid)-grafted carbon nanofibers (CNF-PSSA), benzenesulfonic acid-grafted CMK-5 (CMK-5-BSA), and benzenesulfonic acid-grafted carbon nanotubes (CNT-BSA), have been studied for fructose dehydration to 5-hydroxymethylfurfural (HMF) and fructose alcoholysis to alkyl levulinate. A study for optimizing the reaction conditions such as the catalyst loading, the reaction time, and the temperature has been performed. Under the optimal conditions, high HMF and ethyl levulinate yields of up to 89% and 86%, respectively, are obtained. The catalytic activities of C-SO3H for the conversions of fructose into both HMF and ethyl levulinate follow the order of their acid strength. The relationship between the catalytic activity and acid density of C-SO3H shows a linear correspondence in the fructose dehydration to HMF. The facile separation, ease of recovery, and high thermal stability make the developed C-SO3H efficient and environment-friendly catalytic materials for transforming biomass carbohydrate into fine chemicals. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c3gc41139g |
| WOS Subject Extended | Chemistry |
| WOS Keyword | ETHYL LEVULINATE ; IONIC LIQUIDS ; METHYL LEVULINATE ; FURFURYL ALCOHOL ; MESOPOROUS CARBON ; AMORPHOUS-CARBON ; BIPHASIC SYSTEM ; SULFURIC-ACID ; BIOMASS ; DEHYDRATION |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000325593600034 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10098 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Ruliang,Chen, Jinzhu,Huang, Xing,et al. Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials[J]. GREEN CHEMISTRY,2013,15(10):2895-2903. |
| APA | Liu, Ruliang,Chen, Jinzhu,Huang, Xing,Chen, Limin,Ma, Longlong,&Li, Xinjun.(2013).Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials.GREEN CHEMISTRY,15(10),2895-2903. |
| MLA | Liu, Ruliang,et al."Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials".GREEN CHEMISTRY 15.10(2013):2895-2903. |
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