Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts | |
Zhang, Xinghua1,2 ; Zhang, Qi1; Wang, Tiejun1; Ma, Longlong1; Yu, Yuxiao1,2; Chen, Lungang1
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| 2013-04-01 | |
| Source Publication | BIORESOURCE TECHNOLOGY
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| Volume | 134Pages:73-80 |
| Abstract | Inexpensive non-sulfided Ni-based catalysts were evaluated for hydrodeoxygenation (HDO) using guaiacol as model compound. SiO2-ZrO2 (SZ), a complex oxide synthesized by precipitation method with different ratio of Si/Zr, was impregnated with Ni(NO3)(2)center dot 6H(2)O and calcined at 500 degrees C. Conversion rates and product distribution for guaiacol HDO at 200-340 degrees C were determined. Guaiacol conversion reached the maximum at 300 degrees C in the presence of Ni/SZ-3. When HDO reaction was carried out with real lignin-derived phenolic compounds under the optimal conditions determined for guaiacol, the total yield of hydrocarbons was 62.81%. These hydrocarbons were comprised of cyclohexane, alkyl-substituted cyclohexane and alkyl-substituted benzene. They have high octane number, would be the most desirable components for fungible liquid transportation fuel. (C) 2013 Elsevier Ltd. All rights reserved. |
| Subtype | Article |
| Keyword | Sio2-zro2 Phenolic Compounds Hydrodeoxygenation (Hdo) Hydrocarbon |
| WOS Headings | Science & Technology ; Life Sciences & Biomedicine ; Technology |
| DOI | 10.1016/j.biortech.2013.02.039 |
| WOS Subject Extended | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| WOS Keyword | NOBLE-METAL CATALYSTS ; BIO-OIL ; BIOMASS ; HYDROGENOLYSIS ; CONVERSION ; PYROLYSIS ; ZIRCONIA ; GUAIACOL ; SULFIDE ; ALKANES |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| WOS ID | WOS:000328512800002 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10084 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,et al. Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts[J]. BIORESOURCE TECHNOLOGY,2013,134:73-80. |
| APA | Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,Ma, Longlong,Yu, Yuxiao,&Chen, Lungang.(2013).Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts.BIORESOURCE TECHNOLOGY,134,73-80. |
| MLA | Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts".BIORESOURCE TECHNOLOGY 134(2013):73-80. |
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