Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts | |
Yu Yu-Xiao1,2; Zhang Xing-Hua1,2 ; Wang Tie-Jun1; Xu Ying1; Ma Long-Long1; Zhang Qi1; Zhang Li-Min3
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| 2013-09-10 | |
| Source Publication | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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| Volume | 34Issue:9Pages:2178-2183 |
| Abstract | Ni-B amorphous catalysts were prepared by chemical reduction of nickel chloride with potassium borohydride aqueous solution and characterized by X-ray diffraction(XRD), Brunauer-Emmett-Tetter(BET), scanning electron microscopy (SEM), transmission electron microscopy (TEM), inductively coupled plasma (ICP) techniques. The catalytic performances of model compounds and bio-oil to produce saturated alcohols were evaluated in a semi-batch reactor. The results showed that the conversion of model compounds(acetone, furfural and phenol) and the selectivity of saturated alcohols reached 99.99% and 90.00% at 110 degrees C, 4.0 MPa(initial pressure). Under the conditions of 150 degrees C and 4.0 MPa, the yield of saturated alcohols reached 47.54%. High temperature of above 150 degrees C resulted in the transformation of amorphous phase to form crystal, which was attributed to the low catalytic activity. This work provides a new alternative for the production of saturated alcohols from bio-oil. |
| Subtype | Article |
| Keyword | Bio-oil Ni-b Catalyst Aqueous-phase Reforming Saturated Alcohol |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.7503/cjcu20130258 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | ALLOY CATALYST ; PYROLYSIS OIL ; HYDRODEOXYGENATION ; BIOMASS ; HYDROTREATMENT ; PHENOL ; LA |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000328926400026 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10047 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Yu Yu-Xiao,Zhang Xing-Hua,Wang Tie-Jun,et al. Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2013,34(9):2178-2183. |
| APA | Yu Yu-Xiao.,Zhang Xing-Hua.,Wang Tie-Jun.,Xu Ying.,Ma Long-Long.,...&Zhang Li-Min.(2013).Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,34(9),2178-2183. |
| MLA | Yu Yu-Xiao,et al."Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over Ni-B Amorphous Catalysts".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 34.9(2013):2178-2183. |
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